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31Ga Available gallium properties...Gallium atoms have 31 electrons and the shell structure is 2.8.18.3. The ground state electron configuration of ground state gaseous neutral gallium is [Ar].3d10.4s2.4p1 and the term symbol is 2P1/2.
Schematic electronic configuration of gallium. The Kossel shell structure of gallium. Atomic spectrumA representation of the atomic spectrum of gallium. Ionisation Energies and electron affinityThe electron affinity of gallium is 28.9 kJ mol‑1. The ionisation energies of gallium are given below. Effective Nuclear ChargesThe following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.
ReferencesThese effective nuclear charges, Zeff, are adapted from the following references:
Electron binding energies
NotesI am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5). References
Gallium is the chemical element with the atomic number 31 and symbol Ga on the periodic table. It is in the Boron family (group 13) and in period 4. Gallium was discovered in 1875 by Paul Emile Lecoq de Boisbaudran. Boisbaudran named his newly discovered element after himself, deriving from the Latin word, “Gallia,” which means “Gaul.” Elemental Gallium does not exist in nature but gallium (III) salt can be extracted in small amounts from bauxite and zinc ores. Also, it is known for liquefying at temperatures just above room temperature. Gallium is one of the elements originally predicted by Mendeleev in 1871 when he published the first form of the periodic table. He dubbed it ekaaluminum, indicating that it should have chemical properties similar to aluminum. The actual metal was isolated and named (from the Latin Gallia, for France) by Paul-Emile Lecoq de Boisbaudran in 1875. The detective work behind the isolation of gallium depended on the recognition of unexpected lines in the emission spectrum of a zinc mineral, sphalerite. Eventual extraction and characterization followed. Today, most gallium is still extracted from this zinc mineral. Although once considered fairly obscure, gallium became an important commercial item in the '70s with the advent of gallium arsenide LEDs and laser diodes. At room temperature gallium is as soft as lead and can be cut with a knife. Its melting point is abnormally low and it will begin to melt in the palm of a warm hand. Gallium is one of a small number of metals that expands when freezing.
Gallium has a few notable characteristics which are summarized below:
Video 1: the video depicts the solidifying of liquid Gallium in 10x speed. Density of solid Gallium smaller than density of the liquid, so it's expanding during solidification and break the bottle. Video 2: The video shows Gallium melting in your hands due to its melting point.
Gallium usually cannot be found in nature. It exists in the earth's crust, where its abundance is about 16.9 ppm. It is extracted from bauxite and sometimes sphalerite. Gallium can also be found in coal, diaspore and germanite.
Health: While Gallium can be found in the human body in very small amounts, there is no evidence for it harming the body. In fact, Gallium (III) salt is used in many pharmaceuticals, used as treatment for hypercalcemia, which can lead to growth of tumors on bones. Further, it has even been suggested that it can be used to treat cancer, infectious disease, and inflammatory disease. However, exposure to large amounts of Gallium can cause irritation in the throat, chest pains, and the fume it produces can lead to very serious conditions. Semiconductors: Roughly 90-95% of gallium consumption is in the electronics industry. In the United States, Gallium arsenide (GaAs) and gallium nitride (GaN) represent approximately 98% of the gallium consumption. Gallium arsenide (GaAs) can convert light directly into electricity. Further, gallium arsenide is also used in LEDs and transistors.
Gallium has the property to wet porcelain and even glass surfaces. As a result, gallium can be used to create dazzling mirrors. Scientists employ an alloy with Gallium for the plutonium pits of nuclear weapons to stabilize the alloptropes of plutonium. As a result, some have issue with the element. References
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Stephen R. Marsden |